2C = game forcing
3S = (virtually) solid suit, extra values, sets trumps
4C/4H = cue bids. Partnership style is to cue first round controls before second in this type of auction
4NT/5D/5H/5NT = opener has 3 keycards, the queen of trumps, not the king of clubs (responder didn't ask about the king of clubs, that was part of the 5NT bid)
There is a winning lead. Is it possible to work out what it is, and why?

Help

RHO dealt, uncontested auction
1S 2C
3S 4C
4H 4NT
5D 5H
5NT 7S