First thought is VACANT SPACE. If my guess that WEST has the diamond JACK is correct, West has 6 vacant spaces (13-4H-3D) compared to EAST's 10 vacant spaces (13-1H-2D). So the odds strongly favor EAST having the spade ACE (10/16 versus 6/16). That seems odds are 62.5% chance spade ACE is with EAST.
Second thought, West lead from Jxx of diamonds. This is not a particular lead that stood out (in addition, East did not double 2D/4D for lead), so would restricted choice of some sort apply to the opening lead? That is without the spade ace, would WEST have been just as likely to lead a spade (or club)? How much, if any, would you consider the implications of a non-spade lead here? I would guess if WEST didn't have the spade ACE, he would be as likely to lead a spade as any of the other two non-heart suits. I guess, I might place the likelyhood or a spade lead without the ACE at 1/3, but we also know that WEST lacked club and diamond ACE, so if we treat them as equal suits, would this be 50% or so?
Straight up math (vacant space) suggest playing EAST for spade ACE, adding some value for restricted choice on opening lead decreases this advantage. Is it enough to sway you into playing WEST for the spade ACE? Let's assume that WEST would lead a spade 1/3 of the time when he lacked the ACE, does that reduce the chance EAST has the spade ACE from 62.5% of the time (62.5 - 1/3*62.5 = 41.7%)? What if you place the chance at 20% for a spade lead (62.5 - 1/5*62.5=50%).
Any other math considerations? If your opponents got to 6♥ they are going down one. If you play EAST for spade ACE and are wrong, you are down likely 4 or 5. If you play WEST for spade ace you are down two. Does the imp odds -- lose 7 to 9 imps if you guess EAST and are wrong, versus 3 imps if you guess WEST and are wrong factor in at all (assuming opponents are in 6♥).
As an aside, it is somewhat fun to see how to make this hand if you do decide to play WEST for the Spade ACE.

Help

2♣=2♦
3N=4♦
4♥=5N
6N=all pass
Opening lead ♦5.
T1. D5-T-3-2
T2. H2-Q-A-3
T3. DA-7-8-6
T4. HK-5-4-♣3
Diamond lead solved the risk of losing a diamond, the heart queen being singleton gives you 4 but not 5 hearts. The hand is now cold (double dummy) as there is a 100% line if East has the SPADE ACE and a 100% line if WEST has the SPADE ACE. So who has the ACE?